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Extra resources for The General X-Radiation from Mercury Vapor
Liu different temperatures. Spin probes as defined in  are paramagnetic molecules that add non-covalently and may diffuse in the medium. The spin-probe method can also detect molecular motions of solid polymers from an analysis of the EPR spectra of the probe moving with the polymer chain segment. Computer simulations are frequently employed to extract information of the mobility in the low-motional region. We refer to the literature for information about this topic and of modern applications in the study of polymers  and biopolymers [31, 154] using spin labels and spin probes.
In many free radical systems the g-anisotropy is quite small and it is then impossible at X-band to obtain single crystal like ENDOR spectra, which instead are made up of a large number of orientations. Computer simulations are then essential for the analysis. When the nuclear and hyperfine interactions are much weaker than the electronic Zeeman energy a perturbation treatment is applicable. A program developed by Erickson  has been used in the simulations for this chapter. Several nuclei with any value of nuclear spin I can be handled.
Stoll. 1 is based on the original Schonland method as a simplified replacement for software in obsolete code referred to in our previous work . 4), by which three tensor elements with estimated uncertainties were obtained. Measurements in three mutually orthogonal crystal planes were employed to obtain the complete tensor. 55) originally given in different notation in . 56) of the principal directions considered in [28, 46] were not computed, however. We refer to the literature [28, 46, 170] for procedures to obtain the statistical uncertainties from the propagating errors.