Comprehensive Coordination Chemistry II. Transition Metal by J. A. McCleverty, T.J. Meyer

By J. A. McCleverty, T.J. Meyer

Complete Coordination Chemistry II (CCC II) is the sequel to what has develop into a vintage within the box, finished Coordination Chemistry, released in 1987. CCC II builds at the first and surveys new advancements authoritatively in over two hundred newly comissioned chapters, with an emphasis on present developments in biology, fabrics technology and different parts of up to date clinical curiosity.

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Extra resources for Comprehensive Coordination Chemistry II. Transition Metal Groups 7 and 7

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A frequency-dependant peak in out-of-phase AC susceptibility measurement studies as well as magnetic hysteresis loops. The energy barrier for magnetization reversal for the neutral derivatives is $42–50 cmÀ1 (60–72 K) and is the largest observed for any SMM so far. The cyclic voltammogram of the neutral species displays at least two 29 Manganese Mn Mn Mn O O O O O Mn Mn O Mn Mn Mn O O O O Mn O O Mn Mn Mn Figure 11 Core structure of Mn12 complex. quasireversible reduction waves (one- and two-electron reduced).

The [Mn7(3-O)4]13þ core in the anion of (113) consists of two [Mn4(3-O)2]8þ butterfly units fused together by sharing of one wing-tip at each manganese center. 5CH2Cl2Á2H2O (114) was prepared from (Bun4N)[Mn4O2(O2CPh)9(H2O)] and 4 equiv of Me3SiCl in CH2Cl2 in 45–60% yield. 51 Manganese Table 9 Structural parameters for tetranuclear manganese(III)–carboxylato complexes. 825(10) 293 292 296 291 297,376 298 298 299 300 306 52 Manganese t Bu t t Bu O O O O t Bu O O Mn O t O O Mn O Bu O O O Bu Bu t Bu O O t Bu Bu Mn Mn t O O O t O O O Bu O O O Mn Mn t O O Bu O t t Bu O O O t Bu t Bu (109) O N O N Mn nM O O O O Mn Mn O O O O O N O O Mn O O Mn O O O O N O (111) Table 10 Electrochemical properties for tetranuclear manganese(III)–carboxylato butterfly complexes.

935(7) 42 Table 6 Manganese Magnetic properties and related parameters for dinuclear manganese(III)–carboxylato complexes. 75H2O [Mn2O(O2CC6H5)2 (N3)2(bpy)2]ÁMeCNÁ4H2O [Mn2O(OAc)2Cl2(bpy)2]ÁCH3COOHÁH2O [Mn2O(OAc)2(HB(pz)3)2]ÁCH3CN [Mn2O(OAc)2(HB(pz)3)2]Á4CH3CN [Mn2O(OAc)2(tacn)2](ClO4)2 [Mn2O(OAc)2(Me3tacn)2] (ClO4)2 [Mn2O(OAc)2(tacn)(Me3tacn)](ClO4)2 [Mn2O(OAc)2(BBAE)2](ClO4)2 [Mn2O(OAc)2(mpepma)2](PF6)2ÁH2O [Mn2O(OAc)2(TMIP)2](ClO4)2 [Mn2O(OAc)2(tppn)](ClO4)2ÁCH3CN a eff (BM) [Temp. 3] Temp.

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