Chemical Sensors and Microinstrumentation by Royce W. Murray

By Royce W. Murray

content material: Chemical sensors and microinstrumentation : an summary / Royce W. Murray --
New anion- and gas-selective potentiometric sensors / M.E. Meyerhoff, D.M. Pranitis, H.S. Yim, N.A. Chaniotakis, and S.B. Park --
electric homes of phospholipid bilayer membranes measured with a mild addressable potentiometric sensor / George B. Sigal, Dean G. Hafeman, J. Wallace Parce, and Harden M. McConnell --
Electropolymerized movies within the building of biosensors / Robert J. Geise and Alexander M. Yacynych --
Electrochemical sensors in response to polymer motion pictures immobilized via gamma irradiation / Louis A. Coury, Jr., Christos Galiatsatos, Edward W. Huber, Sandra Sponaugle, and William R. Heineman --
Pulse voltammetric biosensing gadget for genuine time selection of a desk bound droplet glucose pattern / Yoshihito Ikariyama, Naoki Shimada, and Shigeru Yamauchi --
Bioelectrochemistry at microelectrodes / H. Allen O. Hill, Napthali P. Klein, A. Surya N. Murthy, and Ioanna S.M. Psalti --
Microelectrodes to probe spatially heterogeneous concentrations / R. Mark Wightman, Leslie J. could, John Baur, David Leszczyszyn, and Eric Kristensen --
A fiber-optic electrode for optoelectrochemical biosensors / Masuo Aizawa, Masaru Tanaka, and Yoshihito Ikariyama --
Fiber-optic- and polymer film-based enthalpimeters for biosensor functions / Raymond E. Dessy, Lloyd Burgess, Larry Arney, and James Petersen --
Vapor detection with floor acoustic wave microsensors / Hank Wohltjen, David S. Ballantine, Jr., and N.L. Jarvis --
Selective dimension of vinyl acetate vapor utilizing a covered floor acoustic wave oscillator : functions to business hygiene / Edward T. Zellers --
Liquid-phase sensors in line with acoustic plate mode units / A.J. Ricco, S.J. Martin, T.M. Niemczyk, and G.C. Frye --
tracking thin-film homes with floor acoustic wave units : diffusion, floor zone, and pore measurement distribution / G.C. Frye, S.J. Martin, A.J. Ricco, and C.J. Brinker --
Elastic houses of skinny polymer movies investigated with floor acoustic wave units / David S. Ballantine, Jr. and Hank Wohltjen --
Sensors in keeping with biomolecules immobilized at the piezoelectric quartz crystal microbalance : detection of glucose utilizing hexokinase / Steven J. Lasky and Daniel A. Buttry --
layout, coaching, and functions of fiber-optic chemical sensors for non-stop tracking / David R. Walt, Christiane Munkholm, Ping Yuan, Shufang Luo, and Steven Barnard --
Poly(vinyl alcohol)-based symptoms for optical pH and Mg(II) sensing / Ma Wangbai, Zhang Zhujun, and W. Rudolf Seitz --
building and characterization of optical sensors with porous polymer movie / Scott M. Stole, Thomas P. Jones, Lai-Kwan Chau, and Marc D. Porter --
Fiber-optic-based biocatalytic biosensors / Mark A. Arnold --
layout issues for antibody-based fiber-optic chemical sensors / Michael J. Sepaniak, Bruce J. Tromberg, Jean-Pierre Alarie, James R. Bowyer, Arthur M. Hoyt, and Tuan Vo-Dinh --
Acetylcholine receptor-mediated optical transduction from lipid membranes / U.J. Krull, R.S. Brown, okay. Dyne, B.D. Hougham, and E.T. Vandenberg --
New advancements and functions of fiber-optic sensors / S.M. Angel, M.N. Ridley, ok. Langry, T.J. Kulp, and M.L. Myrick --
Optical waveguide chemical sensors / John F. Giuliani --
Multidimensional fluorescence with an easy fiber-optic-based probe / Kevin S. Litwiler and Frank V. Bright.

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1M a c e t i c a c i d . While t h e a c e t i c a c i d does permeate t h e gas membrane i n t o t h e r e c i p i e n t s t r e a m , a c e t a t e ions f o r m e d i n t h e r e c i p i e n t s t r e a m go u n d e t e c t e d by t h e Hg(DCC)2-based s u l f i t e s e l e c t i v e s e n s o r . This type of enhanced s e l e c t i v i t y w o u l d be e x t r e m e l y valuable when determining s u l f i t e s i n wine-vinegar o r other samples t h a t contain v o l a t i l e acidic species Differential Detectors w i t h Gas Sensin E n h a n c e d Gas S e n s i t i v i t y .

Indeed, r e c o n f i g u r i n g t h e new s u l f i t e p o l y m e r i c membrane e l e c t r o d e a s a d e t e c t o r i n a f l o w - t h r o u g h gas phase s n i f f i n g arrangement (8) s h o u l d enable t h e continuous and s e l e c t i v e d e t e c t i o n o f t r a c e l e v e l s o f ambient SO2. The s e n s i t i v i t y o f t h i s a n d o t h e r gas s e n s i n g e l e c t r o d e s y s t e m s may be e n h a n c e d b y t a k i n g advantage of the novel differential cell concept, i n t r o d u c e d h e r e f o r t h e d e t e c t i o n o f d i s s o l v e d ammonia.

L e t us c o n s i d e r t h e c a s e where t h e b i a s p o t e n t i a l i s s t e p p e d w i t h t i m e . I m m e d i a t e l y a f t e r t h e p o t e n t i a l s t e p , t h e new b i a s p o t e n ­ t i a l w i l l be d i s t r i b u t e d a c r o s s t h e c a p a c i t a n c e s w i t h t h e t i m e c o n s t a n t %i ( E q u a t i o n 5) . C j i s t h e t o t a l c a p c i t a n c e o f t h e i n s u l a t o r i n c o n t a c t w i t h e l e c t r o l y t e and Co i s t h e t o t a l c a p a c i t a n c e o f t h e d e p l e t i o n r e g i o n under t h e e l e c ­ t r o l y t e ( t h e r e f o r e Ct i s c a l c u l a t e d f o r t h e a r e a o f t h e semiconductor i n c o n t a c t w i t h s o l u t i o n and not j u s t t h e i l l u m i n a t e d a r e a as i n E q u a t i o n 4 ) .

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