By Stanley M. Roberts, Ivan V. Kozhevnikov, Eric Derouane(eds.)
The chemist has an enormous variety of high-tech catalysts to exploit whilst operating in fine chemical synthesis however the catalysts are mostly challenging to take advantage of and require either time, ability and adventure to deal with adequately. The Catalysts for superb Chemical Synthesis series contains validated and confirmed tactics which provide a different variety assets for chemists who paintings in natural chemistry.
"... of significant worth to artificial natural chemists..." (The Chemists, summer time 2003)
quantity three within the sequence specializes in catalysts for carbon-carbon bond formation and provides useful and detailed protocols on how one can use subtle catalysts by way of the "inventors" and "developers" who created them. The combination of protocols and evaluation commentaries is helping the reader to simply and quickly understand and use the recent high-tech catalysts.Content:
Chapter 1 issues of commercial high-quality Chemical Synthesis (pages 1–12): Mark W. Hooper
Chapter 2 Alkylation and Allylation adjoining to a Carbonyl team (pages 13–33): Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani, Michael North, Jose A. Fuentes, Barry Lygo and Benjamin I. Andrews
Chapter three uneven Alkylation or Amination of Allylic Esters (pages 35–57): Maria Zablocka, Marek Koprowski, Jean?Pierre Majoral, Mathieu Achard, Gerard Buono, Jerome Bayardon, Denis Sinou, Matthias Lotz, Gernot Kramer, Katja Tappe, Paul Knochel, Pierluigi Barbaro, Claudio Bianchini, Giuliano Giambastiani and Antonio Togni
Chapter four Suzuki Coupling Reactions (pages 59–90): Ana S. Abreu, Paula M. T. Ferreira, Maria?Joao R. P. Queiroz, Jie Wu, Lisha Wang, Reza Fathi, Zhen Yang, Ramon E. Huertas, John A. Soderquist, Tatsuo Ishiyama, Norio Miyaura, Bin Tao, David W. Boykin, Colin Baillie, Lijin Xu, Jianliang Xiao, Matthew L. Clarke, J. Derek Woollins, Nicholas Marion, Oscar Navarro, Roy A. Kelly and Steven P. Nolan
Chapter five Heck Coupling Reactions (pages 91–112): Peter Nilsson, Mats Larhed, Lijin Xu, Jun Mo, Jianliang Xiao, Tim G. Kilroy, Yvonne M. Malone and Patrick J. Guiry
Chapter 6 Sonogashira Coupling Reactions (pages 113–125): Anupama Datta, Herbert Plenio, Chih?An Lin and Fen?Tair Luo
Chapter 7 Cross?Coupling Reactions (pages 127–153): Jun Terao, Nobuaki Kambe, Luis A. Sarandeses, Jose Perez Sestelo, Bryan A. Frieman, Bruce H. Lipshutz, John Mancuso, Masahiro Yoshida and Mark Lautens
Chapter eight Regioselective or uneven 1,2?Addition to Aldehydes (pages 155–168): Kui?Thong Tan, Shu?Sin Chng, Hin?Soon Cheng, Teck?Peng Loh, Jens Rudolph, Carsten Bolm, Marco Lombardo, Sebastiano Licciulli, Stefano Morganti and Claudio Trombini
Chapter nine Olefin Metathesis Reactions (pages 169–180): Syuzanna Harutyunyan, Anna Michrowska, Karol Grela, Stephen J. Connon, Aideen M. Dunne, Siegfried Blechert, G. Bhaskar and B. Venkateswara Rao
Chapter 10 Cyclisation Reactions (pages 181–200): Jaime Blanco?Urgoiti, Gema Dominguez, Javier Perez?Castells, Ligang Zhao, Xiyan Lu, Minsheng He, Aiwen Lei, Xumu Zhang, Hiroshi Shinokubo, Koichiro Oshima, Antonio Rosales, Juan M. Cuerva and Enrique Oltra
Chapter eleven uneven Aldol and Michael Reactions (pages 201–223): Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai, Zhuo Tang, Liu?Zhu Gong, Ai?Qiao Mi, Yao?Zhong Jiang, Masahito Watanabe, Kunihiko Murata and Takao Ikariya
Chapter 12 Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions (pages 225–250): Bernhard Breit, Martin Wills, Simon W. Breeden, Stefania Cserepi?Szucs, Jozsef Bakos, C. Ramesh, Y. Kubota, Y. Sugi, Tomoko Matsuda, Tadao Harada, Toru Nagasawa and Kaoru Nakamura
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Extra info for Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions, Volume 3
Sample text
References . . . . . . . . . . . . . . . . . . . . . . . . . CHIRAL FERROCENYL-IMINO PHOSPHINES AS LIGANDS FOR PALLADIUM-CATALYSED .. 47 .. 47 .. .. 49 50 51 PIERLUIGI BARBARO, CLAUDIO BIANCHINI, GIULIANO GIAMBASTIANI and ANTONIO TOGNI . . 51 CATALYSIS ENANTIOSELECTIVE ALLYLIC ALKYLATIONS Catalysts for Fine Chemical Synthesis, Vol. 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions Edited by S. M. Roberts, J.
ASYMMETRIC PHASE-TRANSFER CATALYSED ALKYLATION OF GLYCINE IMINES USING CINCHONA KETONES VIA CARBON-HYDROGEN BOND CLEAVAGE .... 14 14 .... 16 . . 17 18 19 21 . . . . . . COPPER-SALEN COMPLEX AS A PHASE TRANSFER CATALYST 21 22 23 24 26 27 ALKALOID DERIVED QUATERNARY AMMONIUM SALTS BARRY LYGO and BENJAMIN I. ANDREWS . . . . . . . . . . . . . . . . 2]octane bromide . 3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate . . . . . 4 Conclusion . . .
0 RÀ ÀCHÀ ÀR ÀCHÀ olefin þ CO þ H2 syngas ! RÀ ÀCH2À ÀCHðCHOÞÀ ÀR0 aldehyde This is followed by a hydrogenation reaction, which is carried out in the vapour or liquid phase over heterogeneous catalyst RÀ ÀCH2À ÀCHðCHOÞÀ ÀR0 aldehyde þ H2 ! g. Heptenes ! iso-Octanol, Octenes ! iso-Nonanol, Nonenes ! iso-Decanol Unligated rhodium has the ability to hydroformylate a wide range of different olefins, both branched internal forms as well as linear. Virtually no water is used or created in the process (unlike a cobalt-catalysed system which needs water for catalyst recovery).