By David R. Corey, Ronald N. Zuckermann, Peter G. Schultz (auth.), Professor H. Dugas (eds.)
Contents: D.R. Corey, R.N. Zuckermann, P.G. Schultz, Berkeley, CA: Hybrid Enzymes and the Sequence-Specific Cleavage of Nucleid Acids.- S.C. Zimmerman, Urbana, IL: Molecular Tweezers: artificial Receptors for pi-Sandwich Complexation of fragrant Substrates.- Y. Murakami, Fukuoka, Japan; J. Kikuchi, Saga, Japan: Supramolecular Assemblies Formed with artificial Peptide Lipids. practical types of Biomembranes and Enzymes.- A.D. Hamilton, Pittsburgh, PA: Synthetic experiences on Molecular Recognition.- J. Chin, M. Banaszczyk, V. Jubian, J.H. Kim, okay. Mrejen, Montreal: Artificial Hydrolytic Metalloenzymes: A Unified Approach.- J.-P. Sauvage, C. Dietrich-Buchecker, Strasbourg: Interlocked and Knotted jewelry in Biology and Chemistry.
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Additional info for Bioorganic Chemistry Frontiers
4 Complexation by Molecular Tweezers. . . . . . . . . . . 45 45 46 47 50 5 Complexation of Nucleotide Bases Using Hydrogen Bonding and n-Stacking. . . . . . . . . . . . . . . . . . .. 1 Introduction...... . . . . . . . . . . . . . . . . . .. 2 Receptors That Use Only Hydrogen Bonding Forces. . . . . 3 Receptors That Use Hydrogen Bonding Forces and a Single n-Stacking Interaction . . . . . . . . . . . . . . . . . 55 55 57 58 Bioorganic Chemistry Frontiers, Vol.
Green PJ, Pines 0, Inouye M (1986) Ann Rev Biochem, 55: 569 60. Zuckermann R, Corey DR, Schultz PG (1987) Nucleic Acid Res, 15: 5305 61. Corey DR, Schultz PG, unpublished results 62. Tucker PW, Hazen EE, Cotton FA (1978) Mol Cell Biochem, 22: 67 63. Tucker PW, Cotton FA, Hazen EE (1979) Mol Cell Biochem, 23: 3 64. Tucker PW, Cotdon FA, Hazen EE (1979) Mol Cell Biochem, 23: 65. Tucker PW, Hazen EE, Cotton FA (1979) Mol Cell Biochem, 23: 131 66. (a) Serpersu EH, Shortie D, Mildvan AS (1987) Biochemistry, 26: 1289; (b) Ibid (1986) 25: 68 67.
The overall energy of interaction is not often broken down into these components since there is no simple experimental method for determining their individual contributions to the overall complex stability . It is generally agreed that the charge transfer component, responsible for the often intense coloration of EOA complexes, is a minor contributor to its stability . The stability of EOA complexes is particularly sensitive to solvent. 4 M- 1 in dichloromethane solution . While this comparison is an extreme one, the data in Table 1 Table 1.