Aerothermochemistry by Gregorio Millán Barbany

By Gregorio Millán Barbany

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Let comeback on the criterion energy storage density which brings controversy in some storage material discussion. It is most valuable characteristic of a thermal energy storage system. In the following different used terms of energy density are clarified: 1. the theoretical energy density (kJÁkg−1), widely used for sorption systems, is the maximal energy density of the material considering the porosity; 2. The mass energy density (kJÁkg−1), which is the ratio between the reaction enthalpy and the molecular mass; 3.

5 Necessary multidisciplinary field to the development of a TESS based on chemical reactions (adapted from Pardo et al. 2014) with some cogenerations. Then, different storage systems are reviewed and the reason of selecting thermochemical system is highlighted. Finally, some examples of systems are shown and thermodynamic study performed, followed by brief overview of heat and mass transfer with sorption and chemical reaction. The third chapter shows first, a short comparative study between different reactors for such thermochemical storage system.

Picture adapted from (Webber 2013) charging and discharging phases, hence the name thermal battery. The aim is to understand those phases in which chemical reaction with heat and mass transfer are coupled, so that prediction and optimisation can be made. As thermochemical storage systems are still at a very early stage of development, most of the studies are limited to laboratory scale. Considerable amount of time, money and efforts are required before a commercially viable system becomes operational.

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