By Newton [Ed] Friend
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Extra resources for A textbook of inorganic chemistry vol.VII part III Chromium and its congeners
From a practical standpoint it is convenient to consider three areas of the subject. (i) The environment we create for our work, that is the layout of the plant and services. (ii) The way in which the three phases involved in the hydrogenation reaction, hydrogen gas, liquid oil and solid catalyst are brought together in bulk, that is the design of the autoclave or hydrogenation vessel. (iii) The behaviour of the molecules when they have reached the position of being able to react with one another at the catalyst surface and what these several reactions may be.
Methyl linoleate reacts with singlet oxygen at a rate more than 15000-fold greater than it does with ground state oxygen. Also, specific enzymes such as lipoxygenases can catalyse hydroperoxide formation. These occur particularly in leguminous seeds, and is one of the enzymes which is inactivated by blanching. There are thus, incidentally, three ways by which metalloproteins can promote lipid oxidation: through their native action, through the denatured molecule acting directly on a lipid reactant, and as a photosensitiser.
Significant variations are found in the percentage content of the above acids in the sn 1- 2- and 3-positions of the triglycerides of the oil from the same country. There are recognisable differences in the percentage composition of the same fatty acid in the same sn position of the triglycerides of the oils from the two countries. 2 Stereospecific Analysis of Lard 19 The total fatty acid composition found is similar to that reported 14 for pig outer back fat, using an old, and slightly different, method.